How do I activate SMTP authentication in Outlook 2007?
Here you can find a detailed manual how you can activate the SMTP authentification in Outlook 2007.
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Call up the account settings under Tools, Account settings...
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Click on "Change"
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Click on "More settings"
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Click on "Outgoing Server"
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Activate the setting "My outgoing server (SMTP) requires authentication" and "Use same settings as my incoming server"